Β§7.3–7.4Compatible Observables and Commutators

Part IV Phillips pp. 141–146 Β· ~18 min read

  • compatible observables
  • commutator
  • canonical commutation relation

One line of algebra replaces every case-by-case argument about which quantities can be sharp together. Two observables are compatible exactly when their operators commute.

Β§7.2 found that position and momentum have eigenfunctions that cannot both be sharp β€” but only by inspecting each in turn. This section supplies the general test, and it is one line of algebra.

The answer will be the sharpest statement in the book: [x^,p^]=iℏ[\hat x,\hat p] = i\hbar, from which the uncertainty principle follows as a theorem rather than an experimental fact.

7.3 How much has to be specified?

Classically, a particle in one dimension needs two numbers β€” position and momentum β€” and from them every other dynamical quantity follows. In three dimensions it needs six.

Quantum mechanically the count is different, and smaller:

How many numbers specify a state?

⇅classical⇅quantum⇅
a particle in 1-D: and β“˜β“˜
a particle in 3-D: and β“˜β“˜
the usual choiceposition and velocityβ“˜energy, and two moreβ“˜

Click any cell for why. The quantum column is smaller, and that is not a loss of information β€” it is that the extra classical numbers were never simultaneously meaningful.

Observables that can be specified together are called compatible observables , and a set of them large enough to fix the state uniquely is a complete set of compatible observables . What Β§7.3 does not yet supply is a way to tell which observables are compatible. That is Β§7.4.

7.4 The commutator

The commutator of two operators is defined as

[A^,B^]=A^B^βˆ’B^A^(7.15)[\hat A,\hat B] = \hat A\hat B - \hat B\hat A\tag{7.15}

The claim β€” proved for x^\hat x and p^\hat p below, and true in general β€” is that A^\hat A and B^\hat B describe compatible observables if [A^,B^]=0[\hat A,\hat B] = 0 and incompatible observables if [A^,B^]β‰ 0[\hat A,\hat B] \ne 0.

Equation (7.15) β€” a definition that does not look like it says anything

symbol
is
apply BΜ‚ first, then Γ‚. Operator products read right to left, like function composition β€” and like matrix multiplication, which is what they are.
units
dimensionless
type
operator

Click any symbol to see what it is, what units it carries, and what kind of object it is once you put it in an array.

Compatible, commuting, sharing an eigenbasis β€” one statement, three ways

the commutator [Γ‚, BΜ‚]

0.000.000.000.000.000.000.000.000.00

largest entry 0.0000

eigenbasis overlap |⟨aᡒ|bⱼ⟩|²

0.001.000.001.000.000.000.000.001.00

one 1 per row β€” they share a basis

Compatible. The commutator is exactly zero and the overlap matrix is a permutation β€” each eigenvector of Γ‚ is also an eigenvector of BΜ‚. A state can have both observables sharp at once, and measuring one does not disturb the other.

Drag the knob and watch the two panels fail together. There is no angle at which the commutator vanishes but the bases differ, or the bases coincide but the commutator does not vanish. Compatible, commuting, and sharing an eigenbasis are one fact wearing three names β€” and the linear-algebra theorem behind it is that two Hermitian matrices are simultaneously diagonalizable if and only if they commute.

Γ‚ = diag(1, 2, 5) fixed; BΜ‚ starts as diag(3, βˆ’1, 4) and is rotated in the 1–2 plane. Eigenvectors by a Jacobi sweep, so the overlap matrix is computed, not asserted.

The canonical commutation relation

Apply (x^p^βˆ’p^x^)(\hat x\hat p - \hat p\hat x) to an arbitrary Ξ¨(x,t)\Psi(x,t) and use the product rule:

Deriving Eq. (7.17) β€” three lines, and the middle one is the product rule

step 1 of 4

This is the single most consequential calculation in the book, and it is shorter than most of the algebra in chapter 5.

  1. 1Apply the operators in one order. xΜ‚ is multiplication, so it just sits in front β€” nothing interesting happens.

[x^,p^]=iℏ(7.17)[\hat x,\hat p] = i\hbar\tag{7.17}

This is the canonical commutation relation , and the book says outright that it is β€œso important in quantum mechanics” that it earns a name of its own.

Why no state has both

Assume the impossible: a simultaneous eigenfunction ψxβ€²pβ€²\psi_{x'p'} with

x^ψxβ€²pβ€²=xβ€²Οˆxβ€²pβ€²andp^ψxβ€²pβ€²=pβ€²Οˆxβ€²pβ€²(7.18)\hat x\psi_{x'p'} = x'\psi_{x'p'}\qquad\text{and}\qquad \hat p\psi_{x'p'} = p'\psi_{x'p'}\tag{7.18}

Act on it with the commutator two ways. Using Eq. (7.18):

[x^,p^]ψxβ€²pβ€²=(xβ€²pβ€²βˆ’pβ€²xβ€²)ψxβ€²pβ€²=0[\hat x,\hat p]\psi_{x'p'} = (x'p' - p'x')\psi_{x'p'} = 0

because xβ€²x' and pβ€²p' are numbers, and numbers commute. Using Eq. (7.17):

[x^,p^]ψxβ€²pβ€²=iβ„β€‰Οˆxβ€²pβ€²[\hat x,\hat p]\psi_{x'p'} = i\hbar\,\psi_{x'p'}

Both are correct, so iβ„Οˆxβ€²pβ€²=0i\hbar\psi_{x'p'} = 0, so ψxβ€²pβ€²=0\psi_{x'p'} = 0 everywhere.

And the uncertainty principle follows

Define the deviation operators Ξ”x^=x^βˆ’βŸ¨x⟩\widehat{\Delta x} = \hat x - \langle x\rangle and Ξ”p^=p^βˆ’βŸ¨p⟩\widehat{\Delta p} = \hat p - \langle p\rangle. Since ⟨x⟩\langle x\rangle and ⟨p⟩\langle p\rangle are numbers, they commute with everything, so

[Ξ”x^,Ξ”p^]=iℏ(7.19)[\widehat{\Delta x},\widehat{\Delta p}] = i\hbar\tag{7.19}

Then the Schwarz inequality β€” built in problems 5 and 6 β€” gives

(Ξ”x)2(Ξ”p)2β‰₯14βˆ£βˆ«Ξ¨βˆ—[Ξ”x^,Ξ”p^]Ψ dx∣2=ℏ24(\Delta x)^2(\Delta p)^2 \ge \frac14\left|\int\Psi^*[\widehat{\Delta x},\widehat{\Delta p}]\Psi\,\mathrm dx\right|^2 = \frac{\hbar^2}{4}

and therefore

Ξ”x Δpβ‰₯ℏ2\Delta x\,\Delta p \ge \frac{\hbar}{2}

Three dimensions, and a set that does commute

The book’s example: x^\hat x, y^\hat y and p^z\hat p_z. Since p^z\hat p_z differentiates only zz, and xx and yy are constants as far as it is concerned, the product rule generates nothing:

x^p^zΞ¨=βˆ’iℏ xβˆ‚Ξ¨βˆ‚z=p^zx^Ξ¨\hat x\hat p_z\Psi = -i\hbar\,x\frac{\partial\Psi}{\partial z} = \hat p_z\hat x\Psi

so [x^,y^]=[x^,p^z]=[y^,p^z]=0[\hat x,\hat y] = [\hat x,\hat p_z] = [\hat y,\hat p_z] = 0 β€” three mutually compatible observables, with simultaneous eigenfunctions

ψxβ€²yβ€²pzβ€²(x,y,z)=Ξ΄(xβˆ’xβ€²) δ(yβˆ’yβ€²) 12πℏeipzβ€²z/ℏ\psi_{x'y'p_z'}(x,y,z) = \delta(x-x')\,\delta(y-y')\,\frac{1}{\sqrt{2\pi\hbar}}e^{ip_z'z/\hbar}

The pattern is the one that matters: x^\hat x and p^x\hat p_x fail to commute, but x^\hat x and p^z\hat p_z commute perfectly. Incompatibility is a property of a pair, not of position and momentum as categories. You may know exactly where a particle is along xx while knowing exactly how fast it moves along zz.

Where this goes next

Β§7.5 asks what happens when an observable commutes with the Hamiltonian in particular β€” and the answer is that its expectation value never changes. Conservation laws turn out to be commutators that vanish, and the vanishing traces back to a symmetry of H^\hat H.

Check yourself

0 / 6 answered

  1. In the widget's first view, drag BΜ‚ away from Γ‚ and watch both panels.

    1.The commutator grows and the overlap matrix spreads out at the same time. What does that demonstrate?

  2. 2.The derivation of takes three lines. Where does the actually come from?

  3. 3.Assuming a simultaneous eigenfunction of and leads to . What has been proved?

  4. 4.Confining an electron to gives . What should you conclude?

  5. 5.The Compute block shows a naive matrix check of failing with an error of 1.0. Why?

  6. 6. but . What does that tell you about incompatibility?