Β§5.2bTunnelling Electrons and Tunnelling Protons

Part III Phillips pp. 99–103 Β· ~26 min read

  • scanning tunnelling microscope
  • Gamow energy
  • nuclear fusion

One exponent decides everything on this page. Differentiate it and you have a microscope; integrate it over a Coulomb barrier and you have a star.

Β§5.2a ended with a formula and a warning: TT depends on the barrier through eβˆ’2Ξ²ae^{-2\beta a}, the prefactor cannot matter, and the exponent is the only number worth estimating. That is a statement about arithmetic.

This section is what happens when you put real constants into it. The same formula, evaluated twice β€” once for an electron crossing a vacuum gap, once for a proton crossing the electrostatic repulsion of another proton β€” lands on 2Ξ²aβ‰ˆ102\beta a \approx 10 and on an exponent of about 22. The first number built a microscope that sees individual atoms. The second is why the sun is still burning.

Tunnelling electrons

Put two metal surfaces close together. Each holds electrons in an attractive well; between them is a vacuum gap the electrons have no classical business crossing. That is the barrier of Fig. 5.4 built out of real materials, and Eq. (5.40) applies to it unchanged β€” except that for a gap of any reasonable width eβˆ’2Ξ²ae^{-2\beta a} is very small indeed, so the prefactor may be dropped along with everything else that is not exponential:

T≃eβˆ’2Ξ²awithΞ²=2me(VBβˆ’E)ℏ(5.41)T \simeq e^{-2\beta a}\quad\text{with}\quad \beta = \frac{\sqrt{2m_e(V_B - E)}}{\hbar}\tag{5.41}

Equation (5.41) β€” the same formula with the decoration removed

symbol
is
the width of the vacuum gap between the two metal surfaces. This is the variable the instrument controls, and the only one it needs.
units
type
scalar β€” in practice, under a nanometre

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Differentiating the only thing that matters

Because aa sits in an exponent, the fractional change in TT for a small change in the gap is a constant times Ξ”a\Delta a:

Ξ”TT=βˆ’2β Δa(5.42)\frac{\Delta T}{T} = -2\beta\,\Delta a\tag{5.42}

For a metal needing 4Β eV4\ \mathrm{eV} to release an electron β€” so VBV_B sits about 4Β eV4\ \mathrm{eV} above EE:

Ξ²=2me(VBβˆ’E)β„β‰ˆ1010Β mβˆ’1(5.43)\beta = \frac{\sqrt{2m_e(V_B - E)}}{\hbar} \approx 10^{10}\ \mathrm{m^{-1}}\tag{5.43}

The instrument

The scanning tunnelling microscope β€” Eq. (5.41) with the gap made a function of position

vacancya = 0.600 nm
00.51.01.52.00.580.600.620.640.660.68lateral position of the tip (nm)tip height z (nm)

Constant current: a feedback loop pushes the tip up and down to hold I fixed. Fixing I fixes the gap, and the gap is z βˆ’ h(x), so the tip height is the surface profile β€” the plot is now a picture of the atoms rather than a graph of a current. This is what an STM image actually is, and it is why the vacancy at 1.4 nm reads as a hole rather than as a dip in a signal. Note that nothing was measured directly: the height is inferred entirely from Eq. (5.41).

Ξ² = √(2mβ‚‘Ο†)/Δ§ evaluated in SI, with Ο† the barrier height above the most energetic electrons in the metal β€” the book’s 4 eV by default, giving Ξ² = 1.025e+10 m⁻¹, which is Eq. (5.43)’s β‰ˆ 10¹⁰ m⁻¹. The surface is eight atom sites 0.25 nm apart with one vacancy; the current at every point is Eq. (5.41) and nothing else.

Tunnelling protons

The centre of the sun is an ionized gas of electrons, protons and light nuclei at about 107Β K10^7\ \mathrm{K}. Protons collide constantly, and just occasionally two of them fuse and release the energy that eventually leaves the surface as sunlight. The question is how often β€œoccasionally” is β€” and the classical answer is never.

The two energies that do not match

quantity⇅value⇅
thermal energy of a proton at the solar centreβ“˜β“˜
height of the Coulomb barrier they must crossβ“˜β“˜
classical distance of closest approachβ“˜β“˜
temperature the sun would need, classicallyβ“˜β“˜

Click any cell for where the number comes from. The mismatch in the last row is the problem the rest of this page solves.

Figure 5.5, and the shape of the problem

E=e24πϡ0rC(5.44)E = \frac{e^2}{4\pi\epsilon_0 r_C}\tag{5.44}

Equation (5.44) β€” a definition of the turning point, not a law

symbol
is
the CLASSICAL distance of closest approach: where a proton with energy E runs out of kinetic energy and turns round. It depends on E, so it moves as the gas heats or cools.
units
type
scalar; 1440 fm at 1 keV

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Figure 5.5, at true scale β€” the Coulomb barrier two protons must cross

00.51.01.52.02.53.03.54.0-10123log₁₀ ( r / fm ) β€” separation of the two protonslog₁₀ ( V / keV )Er_N = 2 fmr_C = 1440 fm0.72 MeVclassically forbidden β€” 1438 fm of itfusion
  • V(r) = eΒ²/4πΡ₀r, and the nuclear well below r_N
  • energy of approach E
r_C, Eq. (5.44) 1440 fm
r_C / r_N 720
√(E_G/E) 22.21
T, Eq. (5.50) 2.27e-10

Both axes are logarithmic, which is the only way both landmarks fit on one picture: at 1.00 keV the turning point r_C sits 720Γ— further out than the nuclear radius r_N. The book’s Fig. 5.5 draws them a factor of about four apart, because on a linear axis it has no choice. On these axes the Coulomb potential is a straight line of slope βˆ’1 β€” that is what 1/r is β€” and Eq. (5.44) is no longer a formula to trust but simply the point where that line crosses your energy. Everything hatched between the two is territory a classical proton can never enter, and the protons must cross 1438 fm of it to reach the nuclear well on the left, where fusion happens.

SI units, real constants. The reduced mass is ΞΌ = m_p/2 (footnote 4), the nuclear force range is taken as r_N = 2 fm, and E_G = 493.1 keV comes from Eq. (5.51) evaluated in the component β€” not typed in from the book’s β€œ493 keV”.

Setting up the quantum problem

Two protons with relative energy EE are described by an eigenfunction ψ(r)\psi(\mathbf r) obeying

[βˆ’β„22ΞΌβˆ‡2+V(r)]ψ(r)=Eψ(r)(5.45)\left[-\frac{\hbar^2}{2\mu}\nabla^2 + V(r)\right]\psi(\mathbf r) = E\psi(\mathbf r)\tag{5.45}

where ΞΌ=mp/2\mu = m_p/2 is the reduced mass of the pair. For low-energy protons the relevant eigenfunction has no angular dependence and can be written

ψ(r)=u(r)r(5.46)\psi(\mathbf r) = \frac{u(r)}{r}\tag{5.46}

and then u(r)u(r) obeys a one-dimensional equation:

βˆ’β„22ΞΌd2udr2+V(r)u=Eu(5.47)-\frac{\hbar^2}{2\mu}\frac{\mathrm d^2u}{\mathrm dr^2} + V(r)u = Eu\tag{5.47}

From a square barrier to a Coulomb one

The book does not solve Eq. (5.47). It reasons from Β§5.2a instead, in two steps.

Step one: pretend the barrier is square. A barrier of constant height VBV_B and width rCβˆ’rNr_C - r_N gives u∝eΞ²ru \propto e^{\beta r} in the forbidden region β€” the wave decays as rr decreases, going inward β€” so the probability of getting from rCr_C in to rNr_N is the ratio ∣u(rN)∣2/∣u(rC)∣2|u(r_N)|^2/|u(r_C)|^2:

Tβ‰ƒβˆ£exp⁑[βˆ’Ξ²(rCβˆ’rN)]∣2(5.48)T \simeq \left|\exp[-\beta(r_C - r_N)]\right|^2\tag{5.48}

Step two: admit that it is not square. The Coulomb barrier’s height falls with rr, so Ξ²\beta is a function of position, set at each radius by how far V(r)V(r) exceeds EE there. A varying decay rate accumulates as an integral rather than a product, so the exponent becomes a sum over the barrier:

Tβ‰ƒβˆ£exp⁑[βˆ’βˆ«rNrCβ dr]∣2(5.49)T \simeq \left|\exp\left[-\int_{r_N}^{r_C}\beta\,\mathrm dr\right]\right|^2\tag{5.49}

Doing the integral

From Eq. (5.49) to Eq. (5.50) β€” one move per step

step 1 of 8

The book compresses this into 'by substituting r = r_C cosΒ²ΞΈ, we find that'. It is six lines, and the only approximation is in step 5.

  1. 1Start from Eq. (5.49). The modulus-squared just doubles the exponent, exactly as it did for e^(βˆ’2Ξ²a) in Β§5.2a β€” the probability is the amplitude squared.

    So everything from here is about one integral.

T≃exp⁑[βˆ’(EGE)1/2](5.50)T \simeq \exp\left[-\left(\frac{E_G}{E}\right)^{1/2}\right]\tag{5.50} EG=(e24πϡ0ℏc)22Ο€2ΞΌc2(5.51)E_G = \left(\frac{e^2}{4\pi\epsilon_0\hbar c}\right)^2 2\pi^2\mu c^2\tag{5.51}

The constant EGE_G is the Gamow energy , and for two protons it comes to 493Β keV493\ \mathrm{keV}.

Equations (5.50) and (5.51) β€” one constant, and a square root that changes everything

symbol
is
the fine-structure constant Ξ± = 1/137.036 β€” the same dimensionless number ch01 met in the Bohr atom. Its appearance here is the tell that this is an electromagnetic problem with a quantum length scale in it.
units
dimensionless
type
dimensionless, β‰ˆ 0.0073

Click any symbol to see what it is, what units it carries, and what kind of object it is once you put it in an array.

Where this goes next

Two numbers, from one formula. 2Ξ²aβ‰ˆ102\beta a \approx 10 makes a microscope that maps single atoms; EG/Eβ‰ˆ22\sqrt{E_G/E} \approx 22 makes a star that burns for ten billion years. Nothing separates them except what went into Ξ²\beta.

Problems 5 pushes the second case twice more: problem 7 works the proton–proton estimate through in detail, and problem 8 applies the same Coulomb-barrier integral in reverse β€” to alpha particles escaping a nucleus β€” where the identical exponent explains why radioactive half-lives span twenty orders of magnitude.

Chapter 6 leaves square potentials behind for a smooth one, the harmonic oscillator; the exponential tails into the classically forbidden region that Β§5.1a found on a bound state reappear there unchanged, and so does the technique of reading a wave function’s shape off the sign of Eβˆ’V(x)E - V(x).

Check yourself

0 / 6 answered

  1. Switch the microscope widget to constant-current mode and scan across the surface.

    1.The lower trace stops looking like a current and starts looking like a row of atoms. What is actually being plotted, and why does it reproduce the surface?

  2. 2.A monatomic step on the surface is high. With , by what factor does the tunnelling current change as a constant-height tip passes over it?

  3. 3.The Gamow exponent is . Why a square root, rather than the an activation law would give?

  4. 4.Two protons meet with relative energy , and . What does Eq. (5.50) give?

  5. 5.Page 102 prints Eq. (5.47) as . Without consulting any other source, how can you tell it is a misprint?

  6. Step 5 of the derivation replaces the lower limit with 0, on the grounds that .

    6.What does that assumption cost at solar energies, and how would you find out?